Oxidative addition of a C–Se bond to a PtII centre: contrasting reactions of [MCl2(PhCN)2] (M = Pd, Pt) with cyclohepteno-1,4-diselenin

Bates, CG; Khanna, Pawan K.; Morley, Christopher P.; Vaira, Massimo Di

doi:10.1039/a607904k

Cited by 17 publications

References 15 publications

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NMR of Organoselenium and Organotellurium Compounds

Panda

Singh

2012

Patai's Chemistry of Functional Groups

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This chapter gives a systematic account of and surveys the available data on 77 Se and 125 Te NMR spectra of organochalcogen compounds such as chacogenols, mono and dichalcogenides, chalcogenolates, tetra and hexa substituted chalcogen compounds, chalcogenyl halides, chalcogen‐containing heterocycles and macrocycles, chalcogen‐oxygen/nitrogen compounds, etc. The review is based on the literature from 1985 to 2011 and includes 780 references. The 77 Se/ 125 Te NMR spectra of organochalcogen compounds reveal expansive chemical shifts (δ Se /δ Te ) leading to sharp sensitivity of these nuclei (Se/Te) to their environment such as solvent, temperature, molecular geometry, ligand backbone, oxidation state, chelate ring size, steric strain, etc. This is well illustrated by the advantageous use of this spectroscopy in the successful determination of the solution state structure of several organochalcogen compounds. It is noted that the 125 Te and 77 Se chemical shifts of a large number of structurally similar organotellurium and selenium compounds show linear relationship.

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NMR of Organoselenium and Organotellurium Compounds

Panda

Singh

2012

Patai's Chemistry of Functional Groups

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Stepwise Construction of Oligomeric 1,2‐Diselenolene Platinum(IV) Complexes

et al. 2004

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Von Selen umgebenes Platin: PGSE‐NMR‐Diffusionsstudien an einer Mischung oligomerer 1,2‐Diselenolen‐PtIV‐Komplexe wurden zur Charakterisierung der Spezies in Lösung durchgeführt (siehe Struktur: n=0 (1), n=1 (2), n=2 (3); rot Pt, grün Se, blau N, grau C). Die Ergebnisse sind in Einklang mit den Einkristall‐Röntgenbeugungsstrukturen der chiralen Komplexe {PtIVSe6} (1) und {PtIV2Se10} (2). PGSE=pulse field gradient spin‐echo.

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Stepwise Construction of Oligomeric 1,2‐Diselenolene Platinum(IV) Complexes

Ribas¹,

Dias²,

Morgado³

et al. 2004

Angew Chem Int Ed

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Surrounded by selenium: Pulse field gradient spin‐echo (PGSE) NMR diffusion studies of a mixture of oligomeric 1,2‐diselenolene PtIV complexes are performed to characterize the species in solution (see structure: n=0 (1), n=1 (2), n=2 (3); red Pt, green Se, blue N, gray C). The results are in accord with the single‐crystal X‐ray diffraction structures obtained for the chiral complexes {PtIVSe6} (1) and {PtIV2Se10} (2).

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Oxidative addition of a C–Se bond to a PtII centre: contrasting reactions of [MCl2(PhCN)2] (M = Pd, Pt) with cyclohepteno-1,4-diselenin

Cited by 17 publications

References 15 publications

NMR of Organoselenium and Organotellurium Compounds

NMR of Organoselenium and Organotellurium Compounds

Stepwise Construction of Oligomeric 1,2‐Diselenolene Platinum(IV) Complexes

Stepwise Construction of Oligomeric 1,2‐Diselenolene Platinum(IV) Complexes

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