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2021
DOI: 10.3390/ma14133539
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Oxidation State and Local Structure of Chromium Ions in LaOCl

Abstract: LaOCl doped with 0–10 mol% Cr was synthesized by thermal decomposition of chlorides. X-ray diffraction (XRD) analysis revealed that incorporation of chromium results in a decrease of the lattice parameter a and a simultaneous increase of the lattice parameter c. The local structure of chromium ions was studied with X-ray photoelectron (XPS), X-ray absorption (XANES), multifrequency electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) spectroscopy techniques. It was determined tha… Show more

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Cited by 1 publication
(1 citation statement)
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“…The oxidation state of Cr determines its fate in ecosystems. Chromium exists in various oxidation states, with a range from Cr 2+ to Cr 6+ , but the trivalent and hexavalent forms of Cr are commonly present and are highly stable, showing remarkable effects on organisms [3]. At all the pH levels, Cr 6+ is soluble in water, as Cr 3+ either precipitates in the form of Cr (OH) 3 or adsorbs on the surface of the soil.…”
Section: Introductionmentioning
confidence: 99%
“…The oxidation state of Cr determines its fate in ecosystems. Chromium exists in various oxidation states, with a range from Cr 2+ to Cr 6+ , but the trivalent and hexavalent forms of Cr are commonly present and are highly stable, showing remarkable effects on organisms [3]. At all the pH levels, Cr 6+ is soluble in water, as Cr 3+ either precipitates in the form of Cr (OH) 3 or adsorbs on the surface of the soil.…”
Section: Introductionmentioning
confidence: 99%