Oxidation of organic molecules in homogeneous aqueous solution catalyzed by hybrid biocatalysts (based on the Trojan Horse strategy)

Sansiaume, Elodie; Ricoux, Rémy; Gori, Davide; Mahy, Jean‐Pierre

doi:10.1016/j.tetasy.2010.03.050

Cited by 43 publications

(36 citation statements)

References 35 publications

(38 reference statements)

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“…11b). The catalytic rates were thus improved, but the ee's remained low, witnessing the low influence of the proteic environment [99]. This seems to show the limitations of this antibody strategy, at least for heme complexes.…”

Section: Incorporation Of a Coordination Complex Into An Antibodymentioning

confidence: 94%

Coordination complexes and biomolecules: A wise wedding for catalysis upgrade

Hoarau

Hureau

Gras

et al. 2016

Coordination Chemistry Reviews

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Section: Incorporation Of a Coordination Complex Into An Antibodymentioning

confidence: 94%

Coordination complexes and biomolecules: A wise wedding for catalysis upgrade

Hoarau

Hureau

Gras

et al. 2016

Coordination Chemistry Reviews

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“…The Mn(III)-porphyrin 38-estradiol-antibody complexes were found to catalyze the oxidation of styrene by KHSO 5 . Under similar reaction conditions no oxidation was observed with complex 38 alone [36]. Likewise a testosterone derivative 5,10,15-tris(4-sulfonatophenyl)-20-(4-phenyl-17′-succininimidyl-testosterone) (39) was prepared using 17-succininimidyltestosterone (37) as starting material.…”

Section: Steroid-porphyrin Conjugates Steroid Hormone-porphyrin Conjumentioning

confidence: 98%

Steroid-photosensitizer conjugates: Syntheses and applications

Osati

Ali

Guérin

et al. 2017

J. Porphyrins Phthalocyanines

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This review focuses on progress in the development of different approaches to the design of steroid ([Formula: see text] estrogens, androgens, cholesterol) conjugates with coordination assemblies of metalloporphyrins, phthalocyanines and related complexes. Porphyrins and phthalocyanines have received considerable attention due to their novel composition, intriguing spectroscopic, photophysical, and redox properties, and potential application in light-harvesting and optoelectronic devices. With the development of more efficient imaging and therapeutic applications, these bio-conjugates are evaluated as multimodality agents (PET, fluorescence imaging) to monitor the mechanism of action of biologically active components in living systems and as agents for molecular recognition, oxygen atom transfer and catalysis. The tetrapyrrole components, which can be coupled via covalent and various non-covalent linkages, may exhibit strong interactions through efficient photo-induced electron and/or energy transfer processes.

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“…[88] This complex did show activity for asymmetric oxidation of thioanisole but only low ee of 11 % (R) was found. [89] Harada and co-workers demonstrated that this approach can be extended to phosphane transition-metal complexes by raising monoclonal antibodies against the complex show in Scheme 16. [90] Several obtained antibodies combined with the diphosphane-rhodium complex were tested for hydrogenation of amino acid precursors.…”

Section: Supramolecular Anchoring Using Antibody Complexesmentioning

confidence: 99%

“…Antibody-based artificial metalloenzymes used for the sulfoxidation of thioanisole using a) a ruthenium porphyrin by Kenin et al [85] b) MP8 [86,87] and c) an iron porphyrin attached to estradiol by the group of Mahy. [88,89] Scheme 16. Rhodium-diphosphane antibody system used by Harada et al for the hydrogenation of amino acid precursors.…”

Section: Supramolecular Anchoring Using Antibody Complexesmentioning

confidence: 99%

Bioinspired Catalyst Design and Artificial Metalloenzymes

Deuss

Heeten

Laan

et al. 2011

Chemistry A European J

181

125

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Many bioinspired transition-metal catalysts have been developed over the recent years. In this review the progress in the design and application of ligand systems based on peptides and DNA and the development of artificial metalloenzymes are reviewed with a particular emphasis on the combination of phosphane ligands with powerful molecular recognition and shape selectivity of biomolecules. The various approaches for the assembly of these catalytic systems will be highlighted, and the possibilities that the use of the building blocks of Nature provide for catalyst optimisation strategies are discussed.

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Oxidation of organic molecules in homogeneous aqueous solution catalyzed by hybrid biocatalysts (based on the Trojan Horse strategy)

Cited by 43 publications

References 35 publications

Coordination complexes and biomolecules: A wise wedding for catalysis upgrade

Coordination complexes and biomolecules: A wise wedding for catalysis upgrade

Steroid-photosensitizer conjugates: Syntheses and applications

Bioinspired Catalyst Design and Artificial Metalloenzymes

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