Oxidation of molecular bromine by uranium hexafluoride in acetonitrile. Preparation and properties of hexafluorouranates(V) containing positive bromine

McGhee, Laurence; Rycroft, David S.; Winfield, John M.

doi:10.1016/s0022-1139(00)82077-1

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Actinide Hexafluorides1

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1988

2014

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Cited by 11 publications

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“…Some of these reactions can indicate the oxidation power, e.g., as compared to the transition metal hexafluorides. UF 6 oxidizes Br 2 in acetonitrile to Br(CH 3 CN) 3 + UF 6 – , so its oxidative power could be compared to that of OsF 6 ; see previous discussion. All three are reduced by NO under formation of NO + AnF 6 – , which is to be expected .…”

Section: Actinide Hexafluoridesmentioning

confidence: 99%

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Molecular Hexafluorides

Seppelt

2014

Chem. Rev.

100

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Section: Actinide Hexafluoridesmentioning

confidence: 99%

“…, 196 so its oxidative power could be compared to that of OsF 6 ; 119 , which is to be expected. 197 With NOF the same products are obtained, except that PuF 6 brings up some NF 3 O under these conditions.…”

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confidence: 96%