Oxidation of dimethylsulphoxide by sodium m-bromobenzene- sulphonamide: A kinetic and mechanistic study

Kinetics of oxidation of d(+)melibiose and cellobiose by N-bromoacetamide using a rhodium(III) chloride catalyst

“…NBA has been used as an oxidant for uncatalysed [8][9][10][11][12] and catalysed [13][14][15][16][17][18] reactions involving transition metals including Ru(III), Ir(III) and Pd(II) as homogeneous catalysts. The coordination chemistry of Rh(III) [19] has drawn considerable attention due to its chemical reactivity, anti-tumour activity, electronic structure and catalytic functions of its complexes with potential industrial applications.…”

Review on Oxidation of Paracetamol

“…15 About the oxidant Chloramine-T (CAT), a byproduct in saccharin manufacture is well known as analytical reagent, and the mechanistic aspects of its reactions have been well-documented. [16][17][18] Chloramine-Ta member in haloamine family is a good oxidising agent in both acidic and alkaline media. CAT undergoes a two-electron change in its reactions resulting in the formation of the reaction product p-toluenesulphonamide and sodium chloride.…”

The Efficient Palladium-Catalyzed Selective t Synthesis of Benzenesulfonic Acids

“…[3,4] Chloramine-B (C 6 H 5 SO 2 NClNa Á 1.5H 2 O or PhSO 2 NClNa or CAB), the N-chloro derivative of sulfonamide, is gaining importance as oxidant and reagent for the synthesis of a variety of organic molecules. Although the mechanistic aspects of many haloamine reactions have been well documented, [4][5][6][7][8][9] similar studies on chloramine-B are sparse. In view of this, there is considerable scope for the study with CAB to get better insight into the speciation of CAB reaction models and to understand its redox chemistry in solutions.…”