Oxidation of Alkyl Radicals by Metal Complexes

Kochi, Jay K.

doi:10.1016/b978-0-408-70318-5.50019-4

Cited by 6 publications

(1 citation statement)

References 61 publications

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“…The resulting orange-brown crystals were collected by filtration, washed repeatedly with water, recrystallized by dissoving in methanol at room temperature, adding water, and chilling to -20°. The resulting orange-yellow crystals (413 mg, 0.90 mmol, 36%) had: ir (CHCL) 3360, 2950, 2860, 2460,1600,1550,1450, 1360,1200,1085, 970 cm-1; deuteriumdecoupled nmr (CDCL) 0.76 (s, 9) 0.78 (obscured), 1.62 (d, 1,7 = 13.1 Hz), 7.1-8.6 (m, 5). A sample of do material prepared in an analogous manner had the following elemental analysis.…”

Section: Methodsmentioning

confidence: 99%

Stereoselective synthesis of 1-substituted organometallic derivatives of 3,3-dimethylbutane-1,2-d2

Bock¹,

Whitesides²

1974

J. Am. Chem. Soc.

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Reactions of /A«eo-3,3-dimethylbutyl-./,2-z/2 brosylate (2) and Inflate (4) with nucleophilic metal-containing species have been used to prepare ery/Aro-3,3-dimethylbutyl-/,2-d^phenyl selenide (3), -pyridinecobaloxime (5), and -cyclopentadienyltricarbonylmolybdenum (6); each reaction takes place with inversion of configuration at carbon. Reaction of 3,3-dimethylbutyl-/,2-i/2 bromide (predominantly erythro) (7) with trimethyltin lithium yields trimethyl(3,3-dimethylbutyl-/,2-¿2)tin (8) with ca. 80% inversion of configuration. Treatment of cyclopentadienyldicarbonyliron zAreo-3,3-dimethylbutyl-/,2-í/2 (1) with mercuric chloride leads to rAra>3,3-dimethylbutyl-/,2-j2-mercuric chloride (9).

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Section: Methodsmentioning

confidence: 99%