1987
DOI: 10.1109/tei.1987.298900
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Oxidation and Water Tree Formation in Service-Aged XLPE Cable Insulation

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Cited by 72 publications
(13 citation statements)
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“…The FTIR difference spectrum of the treed vs. nontreed region for purified LDPE in Figure 16 shows a very distinct carbonyl peak and thus confirms the observations of other authors that water treeing phenomenon is frequently associated with oxidation [17,18]. Initially, binary LPE blends did not reveal any excess oxidation (Figure 16), owing to the high crystallinity of this material as compared with LDPE.…”
supporting
confidence: 84%
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“…The FTIR difference spectrum of the treed vs. nontreed region for purified LDPE in Figure 16 shows a very distinct carbonyl peak and thus confirms the observations of other authors that water treeing phenomenon is frequently associated with oxidation [17,18]. Initially, binary LPE blends did not reveal any excess oxidation (Figure 16), owing to the high crystallinity of this material as compared with LDPE.…”
supporting
confidence: 84%
“…The FTIR spectra obtained for the dried, water treed regions of LPE blends also did not show any presence of water. Thus, the visible water trees in binary LPE blends were not due to chemically bound water as, for example, in some cases of XLPE insulation [17]. Aging lime (h) Figure 15.…”
mentioning
confidence: 97%
“…Polyethylene leads to an increase of conductivity through the formation of chemical compounds such as carbonyl groups which contribute to the hopping sites to the dielectric, i.e. traps of relatively shallow depth [9]. The transport mechanism refers to both the electric field and elevated temperature, which will cause Cu ++ ions from electrode surface to drift along electric field into polymer, at positive polarization of the copper electrode.…”
Section: Resultsmentioning
confidence: 99%
“…Nevertheless, by using FTIR spectroscopy. Garton et al [5] have observed that the Figure 3. Cross-cut bow-tie tree (bush-type) observed at 1.2 mm from the conductor shield in cable RI6.…”
Section: Resultsmentioning
confidence: 99%