A simple method for the determination of doping type in nanomaterials based on electrical response to humidity Appl. Phys. Lett. 101, 142110 (2012) Charge transport in functionalized multi-wall carbon nanotube-Nafion composite J. Appl. Phys. 112, 053706 (2012) Tailoring plasmon resonances in the deep-ultraviolet by size-tunable fabrication of aluminum nanostructures Appl. Phys. Lett. 101, 081110 (2012) A critical evaluation of the 0-3 approach for magnetoelectric nanocomposites with metallic nanoparticles High temperature, solution phase reduction of cobalt chloride in the presence of stabilizing agents was employed to produce magnetic colloids ͑ferrofluids͒ of cobalt nanocrystals. We systematically synthesized and isolated nearly monodisperse nanocrystal samples ranging in size from 2 to 11 nm while maintaining better than a 7% std. dev. in diameter. As synthesized cobalt particles are each a single crystal with a complex cubic structure related to the beta phase of elemental manganese ͑⑀-Co͒. Annealing the nanocrystals at 300°C converts them quantitatively to the more common hexagonal-close-packed crystal form. Deposition of these uniform cobalt particles on solid substrates by evaporation of the carrier solvent results in the spontaneous assembly of two-dimensional and three-dimensional magnetic superlattices ͑colloidal crystals͒. A combination of x-ray powder diffraction, transmission electron microscopy, and superconducting quantum interference device magnetometry were used to characterize both the dispersed nanocrystals and the assembled superlattices.