This paper considers double-diffusive convection in a square cavity filled with a binary gas, due to horizontal opposing temperature and concentration gradients. The effect of Lewis number was considered under the conditions of Prandtl number Pr = 1, buoyancy ratio N = 1, and thermal Rayleigh numbers Ra T = 10 4 and 10 5 . Numerical solutions are obtained by a Chebyshev collocation technique with high resolution. Depending on the Lewis number, three kinds of flow structures are identified: symmetric steady flow, asymmetric oscillatory flow, and symmetric oscillatory flow. Oscillatory flow occurs in the regime of thermal dominant flow, and leads to a periodic change between stable and unstable states in species stratification due to the thermosolutal interaction. © 2000 Scripta Technica, Heat Trans Asian Res, 30(1): [63][64][65][66][67][68][69][70][71][72][73][74][75] 2001