Orthogonal Postsynthetic Copolymerization of Hydrogen‐Bonded Organic Frameworks into a PolyHOF Membrane
Xiao Liu,
Yingxiang Ye,
Xu He
et al.
Abstract:Hydrogen‐bonded organic frameworks (HOFs) have shown promise in various fields; however, the construction of HOF/polymer hybrid membranes that can maintain both structural and functional integrity remains challenging. In this study, we here fabricated a new HOF (HOF‐50) with reserved polymerizable allyl group via charge‐assisted H‐bonds between the carboxylate anion and amidinium, and subsequently copolymerized the HOF with monomers to construct a covalently bonded HOF/polymer hybrid (polyHOF) membrane. The re… Show more
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