Origin of Weak Magnetic Coupling in a Dimanganese(II) Complex Bridged by the Tetrathiafulvalene-Tetrathiolate Radical
Chen-Yu Lien,
Jan-Niklas Boyn,
Sophie W. Anferov
et al.
Abstract:Magnetic exchange coupling (J) between
different
spin centers plays a crucial role in molecule-based magnetic materials.
Direct exchange coupling between an organic radical and a metal is
frequently stronger than superexchange through diamagnetic ligands,
and the strategy of using organic radicals to engender desirable magnetic
properties has been an area of active investigation. Despite significant
advances and exciting bulk properties, the magnitude of J for radical linkers bridging paramagnetic centers is s… Show more
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