Origin of the selectivity differences of aromatic alcohols and amines of different n-alkyl chain length separated with perfluorinated C8 and bidentated C8 modified silica hydride stationary phases
Abstract:Perfluorinated C8-(PerfluoroC8) and bidentate anchored C8-(BDC8)-modified silica hydride stationary phases have been employed for the isocratic separation of homologous phenylalkanols and phenylalkylamines differing in their
n
-alkyl chain length, using aqueous-acetonitrile (ACN) mobile phases of different ACN contents from 10 to 90% (v/v) in 10% increments. These analytes showed reversed-phase (RP) retention behaviour with mobile phases of <40% (v/v) ACN content with both stationary pha… Show more
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