In this work, the DDF-like approach to the pure spinor cohomology is extended to the next ghost number level, the so called antifields. In a direct (supersymmetric) parallel to the bosonic string, some properties of the ghost number two cohomology are derived with the enlargement of the DDF algebra. Also, the DDF conjugates of the b ghost zero mode emerge naturally from the extended algebra and the physical state condition is discussed. Unlike the bosonic string case, the cohomology analysis of the pure spinor b ghost is restricted to BRST-closed states.