Origin of Lasing in Forsterite: Additional Data and Analysis

Meilman, M. L.; Livshitz, M. G.

doi:10.1364/assl.1992.cl10

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2020

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“…Наиболее изучены спектры ЭПР четырехвалентного хрома в кристалле форстерита [8][9][10], есть ряд работ по германатам [7,11,12]. Однако, в кристалле YAG, несмотря на его широкое применение, до сих пор не зарегистрированы спектры Cr 4+ в тетраэдре.…”

Section: Introductionunclassified

Парамагнитный резонанс ионов Cr-=SUP=-4+-=/SUP=- и Mn-=SUP=-2+-=/SUP=- в кристалле Li-=SUB=-2-=/SUB=-CaSiO-=SUB=-4-=/SUB=-

Vazhenin¹,

Shakurov²,

Потапов³

2020

Физика Твердого Тела

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Tetragonal Cr4+ centers (3d2 electron configuration, spin S=1) in the Li2CaSiO4 crystal at different frequencies were detected and studied. The value of splitting at a zero magnetic field was determined. In the area where the positions of the two Cr4+ transitions coincide, the additional signal with inverse phase was observed. For uncontrolled impurity Mn2+ ions (S=I=5/2) the spin Hamiltonian parameters and localization are determined

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