Most Miocene coals in Turkey are of subbituminous to lignite rank. The G6kler coal field in the western part of Turkey contains mainly high sulphur coals of bituminous rank. The chemical characteristics, mineralogical composition and rank of high sulphur coking coals of Middle Miocene age in the coal field are investigated for the first time. A total of 46 channel and core samples were collected from underground mine workings and from boreholes drilled in the coal field.The results of the proximate analyses as well as total sulphur analyses and calorific values on an air-dried basis show on average 1.2% moisture, 22.9% ash, 34.6% volatile matter, 6.9% total sulphur contents and 5850kcalkg -1 calorific value. X-ray powder diffraction studies of the coal samples on an air-dried basis show quartz, pyrite and calcite to be the dominant minerals; kaolinite, hydromuscovite, dolomite, gypsum, iron sulphate hydrate and rarely illite/smectite and feldspar constitute the remainder. Secondary calcite in random fractures surfaces of the coals is especially abundant in samples obtained from an area adjacent to the fault zones. The mean random reflectance values (%Rr) of telocollinite vary between 0.50 and 0.95%. These values show that the rank can be determined as a high volatile bituminous stage. In addition, these coals can form isotropic coke. Fluorescence intensities of sporinite are weak to very weak. The mean random vitrinite reflectance values within the coal field generally increase towards southern parts of the coal field. It is thought that this increase can be related to the recent hydrothermal antimony mineralization in the southeastern parts of the coal field.