Organophosphorus Compounds, XXVI * The Reaction of Diazoketones with Trialkyl Phosphites

Sidky, M. M.; Soliman, F. A.; Kateb, A. A. El

doi:10.1515/znb-1977-1114

Zeitschrift Für Naturforschung B

1977

DOI: 10.1515/znb-1977-1114

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Organophosphorus Compounds, XXVI * The Reaction of Diazoketones with Trialkyl Phosphites

M. M. Sidky

F. A. Soliman

A. A. El Kateb

Abstract: Diazoketones 1, 8, 10 and 14 react with trialkyl phosphites to give different products depending upon the structure of the diazo compound, the type of the solvent and the nature of the phosphite ester used. Possible reaction mechanisms are discussed and the structural assignements are based on analytical, chemical and spectroscopic results.

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General approach for regioselective synthesis of fused phosphono substituted-oxadiazines

Abdou

Ganoub

2000

Heteroatom Chem.

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A series of fused 1,3,4‐oxadiazines were regioselectively prepared in reasonable yields as major products from the reactions of the corresponding α‐carbonyl hydrazones with tetraethyl 1,3‐dithietane‐2,4‐diylidene‐bis(cyanomethylphosphonate) (1). Side products were also observed wherein the dimeric products 8 or 17 and/or different types of N‐heterocycles such as pyrazole 24 or pyridazines 28 or 29 were isolated and identified. A comparative study on the chemistry of 1 toward α‐aminonitrile 30 is also described. © 2000 John Wiley & Sons, Inc. Heteroatom Chem 11:196–204, 2000

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General approach for regioselective synthesis of fused phosphono substituted-oxadiazines

Abdou

Ganoub

2000

Heteroatom Chem.

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ChemInform Abstract: ORGANOPHOSPHORUS COMPOUNDS. PART 26. THE REACTION OF DIAZOKETONES WITH TRIALKYL PHOSPHITES

Sidky¹,

Soliman²,

Kateb³

1978

Chemischer Informationsdienst

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Flüssig-flüssig-Gleichgewichte in den binären Systemen aus Epichlorhydrin und Epibromhydrin mit n-Hexan und n-Heptan

Becker¹,

Kiefer²,

Rhensius³

et al. 1978

Zeitschrift Für Physikalische Chemie

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Organophosphorus Compounds, XXVI * The Reaction of Diazoketones with Trialkyl Phosphites

Cited by 3 publications

References 1 publication

General approach for regioselective synthesis of fused phosphono substituted-oxadiazines

General approach for regioselective synthesis of fused phosphono substituted-oxadiazines

ChemInform Abstract: ORGANOPHOSPHORUS COMPOUNDS. PART 26. THE REACTION OF DIAZOKETONES WITH TRIALKYL PHOSPHITES

Flüssig-flüssig-Gleichgewichte in den binären Systemen aus Epichlorhydrin und Epibromhydrin mit n-Hexan und n-Heptan

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