Organometallic and carbonyl compounds of cadmium: analysis of crystallographic and structural data

Holloway, Clive Ε.; Melnı́k, Milan

doi:10.1016/0022-328x(96)06157-8

Cited by 7 publications

(1 citation statement)

References 40 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In a similar way to e-mail: deposit@chemcrys.cam.ac.uk). Cd(C 6 H 4 CH 2 NMe 2 ) 2 [19] , comparable donor stabilized cadmium [11] [40] and zinc complexes Zn(CH 2 CH 2 CH 2 X) 2 (X ϭ 3. Synthesis of the Complexes NMe 2 , PPh 2 , OMe, SMe) [15] [38] [41] , the coordination sphere Bis(2-diethylaminomethylphenyl)zinc (1a): 2-Diethylaminometharound the metal center is more accurately described as a ylphenyllithium (1) (4.06 g, 24.0 mmol) was dissolved in Et 2 O (100 distorted trigonal bipyramid with one vacancy in the equa-ml) and a solution of ZnCl 2 (1.64 g, 12.0 mmol) in Et 2 O (40 ml) torial plane than as a tetrahedron.…”

Section: Generalmentioning

confidence: 99%

Homoleptic Organometallic Compounds of Zinc, Cadmium, and Mercury, Intramolecularly Stabilized by Amine Ligands

Schumann

Freitag

Girgsdies

et al. 1998

Eur. J. Inorg. Chem.

View full text Add to dashboard Cite

Homoleptic intramolecularly stabilized organozinc, ‐cadmium, and ‐mercury compounds MR2, with R bearing an amino function, have been synthesized from the corresponding metal dichlorides MCl2 and the lithium salts LiC6H4CH2NEt2‐2 (1), LiC6H3(CH2NMe2)2‐2,6 (2), LiC6H3(CH2NEt2)2‐2,6 (3), (LiCH2CH2CH2)2NMe (4), and LiCH2CH2CH2NC5H10 (5). The crystal structures of Hg(C6H4CH2NEt2‐2)2 (1c), [M(CH2CH2CH2)2NMe]2 [M = Zn (4a), Hg (4c)], and of M(CH2CH2CH2NC5H10)2 [M = Zn (5a), Cd (5b)] have been determined by X‐ray diffraction. 4a and 4c form dimers with an unusual coordination number (three) of the central metal.

show abstract

Section: Generalmentioning

confidence: 99%