The authors turn to the consideration of the issue of social intelligence and value orientations of high school students. Speaking about the relevance of the study, the authors indicate that social intelligence and the value orientations provide students with psychological adaptation to new socio-economic conditions and education systems, and participate in the formation of professional self-determination. Considering social intelligence, the authors turn to the interpretation of this concept by researchers E.L. Thorndike, F. Moss and T. Hunt, G. Olport. When considering the concept of “value orientations”, the authors turn to history and give its definition, based on the study of psychological and pedagogical literature. In order to study the social intelligence and value orientations of high school students, the authors conducted an experiment, which is based on a test for the study of social intelligence by J. Guildford and M. O’Sullivan. The students' value orientations were evaluated according to three universal factors: grades (values), strengths (potency) and activity, developed by C. Osgood.