2012
DOI: 10.1002/adma.201104305
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Organic Thermoelectric Materials and Devices Based on p‐ and n‐Type Poly(metal 1,1,2,2‐ethenetetrathiolate)s

Abstract: A series of metal coordination polymers containing 1,1,2,2-ethenetetrathiolate (ett) linking bridge (poly[Ax(M-ett)]) are synthesized. The Seebeck coefficients of these conducting materials are high, and vary according to the center metals and counter cations. The TE device fabricated demonstrates the great potentials of these materials for TE applications.

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Cited by 476 publications
(466 citation statements)
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References 25 publications
(32 reference statements)
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“…While the absolute efficiency values still require further improvement, it is worth looking at the specific power output normalized to the active cross-sectional area of both crystals, as depicted on the right ordinate of Figure 4b. This key parameter for cost-per-watt in waste heat recovery [31] reaches values of 1 mW/cm 2 at Δ = 30 K being three orders of magnitude larger than those of thermoelectric devices based on polymers [2] .…”
mentioning
confidence: 89%
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“…While the absolute efficiency values still require further improvement, it is worth looking at the specific power output normalized to the active cross-sectional area of both crystals, as depicted on the right ordinate of Figure 4b. This key parameter for cost-per-watt in waste heat recovery [31] reaches values of 1 mW/cm 2 at Δ = 30 K being three orders of magnitude larger than those of thermoelectric devices based on polymers [2] .…”
mentioning
confidence: 89%
“…been proposed as potential candidates to meet these challenges showing appreciable low-temperature thermoelectric performance, but unfortunately suffering from low electrical conductivity due to inherent disorder [2][3][4][5] . Herein …”
mentioning
confidence: 99%
“…Conducting polymer TE materials possess the advantages of low κ, good flexibility and low cost in comparison with inorganic materials. [1][2][3][4] Among them, commercially available PEDOT:polystyrenesulfonate (PEDOT:PSS) has received the most attention due to its excellent water processability and high σ ( refs 5-11 ) and is also widely used as an electrode or conductive adhesive material in applications including solar cells, 12,13 organic light-emitting diodes (OLEDs), 14,15 supercapacitors, 16,17 sensors 18,19 and so on. The PSS polyanion enables the formation of aqueous PEDOT:PSS solutions, which benefits both film printing and the synthesis of hybrid materials.…”
Section: Introductionmentioning
confidence: 99%
“…For the three CNTs/Ag 2 Te hybrids, the carrier concentration is higher for samples with more Ag 2 Te. The sample CA-1, which contains most Ag 2 Te, has the largest carrier concentration of 6.591×10 18 We mention that the effect of the irregularities in the nanoparticles positions and in the strengths of the tunneling coupling is different for metallic and insulating samples. If the coupling between the particles is sufficiently strong and the system is well conducting, the irregularities are not very important.…”
Section: Methodsmentioning
confidence: 89%