“…This study points out that subtle structural modulation of the arm length in the resulting conjugated starbursts plays as ignificant impact on the corresponding optoelectronic characteristics, which sheds light on rational design and optimization of the molecular architectures for organic semiconductor lasing. (1,2), Tr2 (3,4), Tr3 (5,6), Tr4 (7,8) films at different thicknesses:120 nm with L = 280 nm for l = 420 nm (1), 150 nm with L = 280 nm for l = 422 nm (2), 120 nm with L = 280 nm for l = 426 nm (3), 150 nm with L = 280 nm for l = 430 nm (4), 120 nm with L = 280 nm for l = 431 nm (5), 150 nm with L = 280 nm for l = 435 nm (6), 120 nm with L = 280 nm for l = 438 nm (7), 150 nm with L = 280 nm for l = 439 nm (8).…”