Organic–inorganic hybrid [NH₃(CH₂)₆NH₃]ZnBr₄ crystal: structural characterization, phase transitions, thermal properties, and structural dynamics

Abstract

Organic–inorganic hybrid [NH3(CH2)6NH3]ZnBr4 crystals were prepared by slow evaporation; the crystals had a monoclinic structure with space group P21/c and lattice constants a = 7.7833 Å, b = 14.5312 Å, c = 13.2396 Å, β = 90.8650°, and Z = 4.

Investigation of structural, optical and electrical conductivity of a new organic inorganic bromide: [C12H17N2]2ZnBr4

“…The structural parameters of the present compound agree well with those found in similar compounds characterized by [ZnBr 4 ] 2− tetrahedral units. 20…”

“…The structural parameters of the present compound agree well with those found in similar compounds characterized by [ZnBr 4 ] 2− tetrahedral units. 20 The two chemically identical monoprotonated cations [C 12 H 17 N 2 ] + are crystallographically independent and are noted respectively: Cation (A) {N1a, N2a} and Cation (B) {N2a, N2b}. The values of C-C and C-N distance, in the two cations, range from 1.284(8) to 1.539 (10) Å while C-C-C and C-C-N angles are between 105.2(7) and 133.3(6) (Table S2) †.…”

Coordination Polymer Based on a Triangular Carboxylate Core {Fe(μ3-O)(μ-O2CR)6} and an Aliphatic Diamine

“…Last year, a work was published where layered lead perovskites were studied, in which the layers were formed with protonated 1,6-diaminohexane bridges [48]. 1,6-diaminohexane can be used to obtain self-assembled hybrid layered molybdates [49], photo-electroactive indium and antimony chalcogenides [50], dynamic organic-inorganic hybrid [H 2 dahx]ZnBr 4 crystals with the ability to control phase transitions [51], and hybrid organic-inorganic borate frameworks [52].…”