Organic group decorated heterogeneous Pd complex on mesoporous silica toward catalytic allylation in aqueous media

Ding, Siming; Kong, Yuanyuan; Manaka, Yuichi; Chun, Wang‐Jae; Tomita, Ikuyoshi; Motokura, Ken

doi:10.1016/j.cattod.2022.06.044

Catalysis Today

2023

DOI: 10.1016/j.cattod.2022.06.044

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Organic group decorated heterogeneous Pd complex on mesoporous silica toward catalytic allylation in aqueous media

Siming Ding

Yuanyuan Kong

Yuichi Manaka

et al.

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2024

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Development of Silica‐Immobilized Material as Heterogeneous Hydrogen Bond Donor (HBD) Catalyst: Synthesis of Cyclic Carbonates from CO₂ and Epoxides

Roy,

Das,

Santra

et al. 2024

ChemistrySelect

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Composite silica materials have been developed by hydrothermal method and utilized as heterogeneous Hydrogen Bond Donor (HBD) catalysts, where the functionalized ketimine derivatives have been immobilized on the solid support. Such functional materials have been found to be efficient catalysts for the synthesis of cyclic carbonates through the installation of CO2 with epoxides. Characterization of these materials was systematically done using various spectroscopic and imaging techniques to confirm the presence of organic compounds on the silica surface. These composite materials exhibited significantly higher catalytic activity as compared to the other homogeneous methods. Additionally, this synthetic process was extremely convenient in terms of all the external parameters such as, solvent free condition at ambient reaction temperature with normal pressure of CO2, very low catalyst loading with proper regeneration and reusability of the catalyst. These facets have definitely made this technique greener and more sustainable.

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Development of Silica‐Immobilized Material as Heterogeneous Hydrogen Bond Donor (HBD) Catalyst: Synthesis of Cyclic Carbonates from CO₂ and Epoxides

Roy,

Das,

Santra

et al. 2024

ChemistrySelect

View full text Add to dashboard Cite

show abstract

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Organic group decorated heterogeneous Pd complex on mesoporous silica toward catalytic allylation in aqueous media

Cited by 1 publication

References 53 publications

Development of Silica‐Immobilized Material as Heterogeneous Hydrogen Bond Donor (HBD) Catalyst: Synthesis of Cyclic Carbonates from CO₂ and Epoxides

Development of Silica‐Immobilized Material as Heterogeneous Hydrogen Bond Donor (HBD) Catalyst: Synthesis of Cyclic Carbonates from CO₂ and Epoxides

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Organic group decorated heterogeneous Pd complex on mesoporous silica toward catalytic allylation in aqueous media

Cited by 1 publication

References 53 publications

Development of Silica‐Immobilized Material as Heterogeneous Hydrogen Bond Donor (HBD) Catalyst: Synthesis of Cyclic Carbonates from CO2 and Epoxides

Development of Silica‐Immobilized Material as Heterogeneous Hydrogen Bond Donor (HBD) Catalyst: Synthesis of Cyclic Carbonates from CO2 and Epoxides

Contact Info

Product

Resources

About

Development of Silica‐Immobilized Material as Heterogeneous Hydrogen Bond Donor (HBD) Catalyst: Synthesis of Cyclic Carbonates from CO₂ and Epoxides

Development of Silica‐Immobilized Material as Heterogeneous Hydrogen Bond Donor (HBD) Catalyst: Synthesis of Cyclic Carbonates from CO₂ and Epoxides