2022
DOI: 10.1039/d1mh01294k
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Organic building blocks at inorganic nanomaterial interfaces

Abstract: Inorganic–organic interfaces: a tutorial on using organic functional groups to enhance the performances and/or enable new functionality of inorganic nanomaterials.

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Cited by 25 publications
(21 citation statements)
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“…We attribute the small k PCT to the extremely weak electronic coupling between the inorganic QD core and M in solution. Either charges must tunnel through the ligand shell to reach M in solution or M must bury itself in the ligand shell to get better electronic overlap …”
Section: Resultssupporting
confidence: 87%
See 1 more Smart Citation
“…We attribute the small k PCT to the extremely weak electronic coupling between the inorganic QD core and M in solution. Either charges must tunnel through the ligand shell to reach M in solution or M must bury itself in the ligand shell to get better electronic overlap …”
Section: Resultssupporting
confidence: 87%
“…Either charges must tunnel through the ligand shell to reach M in solution or M must bury itself in the ligand shell to get better electronic overlap. 43 Importantly, this comparison highlights the practical utility of using CV to measure kPCT in determining the potential of QD donors and molecular acceptors in a photocatalytic reaction scheme. Eq.…”
Section: Results and Discussion Of Photoinduced Charge Transfer To Co...mentioning
confidence: 92%
“…Either charges must tunnel through the ligand shell to reach M in solution or M must bury itself in the ligand shell to get better electronic overlap. 51 𝑘 𝑑𝑖𝑓𝑓 = 4𝜋𝑁 1000 (𝑅 𝑄𝐷 + 𝑅 𝑀 )(𝐷 𝑄𝐷 + 𝐷 𝑀 ) = 2 × 10 10 (𝑀 s) −1 Eq. 4…”
Section: Uncertainty In [Qd*] Results In Uncertain Intrinsic Ratementioning
confidence: 99%
“…By starting with QDs capped with carboxylate ligands, we estimate an approximate equilibrium constant for the ligand exchange with peptoid of 1 . For the QD composition, CdSe and CdS were chosen due to the depth of the existing literature for these materials in diverse solvents, as well as the well-developed knowledge of ligand exchange and binding affinities for many different systems. Cadmium chalcogenides are known to be relatively stable in water without significant surface modification . Using QDs as pendant groups on the peptoids allows for straightforward modification of the peptoids without drastically modifying the synthetic chemistry or reactivity.…”
mentioning
confidence: 99%