Organic additive–copper(II) complexes as plating precursors

Watanabe, Rogério H.; Gois, M. C.; Neto, Benedito dos Santos Lima

doi:10.1016/j.surfcoat.2009.08.020

Cited by 2 publications

(1 citation statement)

References 13 publications

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“…This can be explained by a different coordination environment of Cu(II) in both the samples and points toward the existence of Cu–imidazole interaction in the nanosponges. The cyclic voltammogram recorded for the Cu@iNS solution agrees well with others described for copper electrodeposition and electrodissolution, in which the use of complexing reagents, such as oxalate, amine, and imidazole derivatives, are required …”

Section: Resultssupporting

confidence: 87%

Imidazole‐Grafted Nanogels for the Fabrication of Organic–Inorganic Protein Hybrids

Rodriguez‐Abetxuko

Morant‐Miñana

López‐Gallego

et al. 2018

Adv Funct Materials

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Here, a platform for the development of highly responsive organicinorganic enzyme hybrids is provided. The approach entails a first step of protein engineering, in which individual enzymes are armored with a porous nanogel decorated with imidazole motifs. In a second step, by mimicking the biomineralization mechanism, the assembly of the imidazole nanogels with CuSO 4 and phosphate salts is triggered. A full characterization of the new composites reveals the first reported example in which the assembly mechanism is triggered by the sum of Cu(II)-imidazole interaction and Cu 3 (PO 4 ) 2 inorganic salt formation. It is demonstrated that the organic component of the hybrids, namely the imidazole-modified polyacrylamide hydrogel, provides a favorable spatial distribution for the enzyme. This results in enhanced conversion rates, robustness of the composite at low pH values, and a remarkable thermal stability at 65 °C, exhibiting 400% of the activity of the mineralized enzyme lacking the organic constituent. Importantly, unlike in previous works, the protocol applies to the use of a broad range of transition metal cations (including mono-, di-, and trivalent cations) to trigger the mineralization mechanism, which eventually broadens the chemical and structural diversity of organic-inorganic protein hybrids.

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Section: Resultssupporting

confidence: 87%

Imidazole‐Grafted Nanogels for the Fabrication of Organic–Inorganic Protein Hybrids

Rodriguez‐Abetxuko

Morant‐Miñana

López‐Gallego

et al. 2018

Adv Funct Materials

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Corrosion protection of copper and copper alloys in different corrosive medium using environmentally friendly corrosion inhibitors

2020

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The corrosion mechanism of copper and copper alloy is reviewed. A number of scientific papers have been investigated to determine the corrosion mechanism and protection techniques of copper and copper alloy corrosion. Results have shown that copper can be corroded in an acidic or an alkaline environment, and oxide formation is the corrosion initiation process. The use of corrosion inhibitors is one of several ways of controlling metal corrosion. There are inorganic (toxic) and organic (green) corrosion inhibitors invented so far. Nowadays, environmental issue is a concern of several scientists in the world. From the results of recent scientific papers, green corrosion inhibitors can be used for copper corrosion protection and they are both economical and environmentally safe. Furthermore, future researches are needed to determine more efficient, environmentally friendly corrosion inhibitors for copper and copper alloys.

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Organic additive–copper(II) complexes as plating precursors

Cited by 2 publications

References 13 publications

Imidazole‐Grafted Nanogels for the Fabrication of Organic–Inorganic Protein Hybrids

Imidazole‐Grafted Nanogels for the Fabrication of Organic–Inorganic Protein Hybrids

Corrosion protection of copper and copper alloys in different corrosive medium using environmentally friendly corrosion inhibitors

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