The Xing'an-Inner Mongolia Orogenic Belt (XIMOB) exposed in the eastern section of the Central Asian Orogenic Belt (CAOB) is generally thought to have resulted from closure of the Paleo-Asian ocean [Şengör et al., 1993]. However, the current hot debate is focused on whether the orogen formed through continuous subduction and accretion over a prolonged period of time until the closure of the Paleo-Asian ocean at the Early Triassic [Xiao et al., 2003], or through the subduction of the Paleo-Asian ocean and related collision in the Early-Mid Devonian [Xu et al., 2013], and the tectonic setting in the Late Paleozoic to Mesozoic has been a pivotal issue. In order to establish the tectonic framework and orogenic processes of XIMOB, systemic researches of petrology, geochemistry, phase equilibria and zircon geochronology were carried on the metamorphic rocks in the central Inner Mongolia, such as the Xilingol complex and the low-grade metamorphism in the Carboniferous to Permian sequences along the Solonker suture zone [Dong et al., 1986]. The results suggest that the Xilingol complex is characterized by clockwise P-T evolution with T max condition of 770-790 °C for a pressure of 5-6 kbar, being in typical hightemperature and low-pressure (HT-LP) type; and the low-grade metamorphism along the Solonker suture zone is characterized by clockwise P-T paths with the peak P-T conditions of metabasite and mica-schist being intermediate and low P/T series respectively.