2018
DOI: 10.1002/admi.201701667
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Ordering and Grain Growth in Charged Block Copolymer Bulk Films: A Comparison of Solvent‐Related Processes

Abstract: for ubiquitous nanotechnologies. [1][2][3][4] Thermodynamic incompatibility [5][6][7] drives BCs to order into an assortment of classical (e.g., spherical, cylindrical, or lamellar) or spatially complex (e.g., gyroid, [8] helical, [9] or Fddd [10,11] ) morphologies. Judicious chemical design of BCs in terms of factors, such as chemical constitution [12][13][14] and molecular composition, weight and architecture, [15] as well as targeted blending with solvents [16,17] or other macromolecules, [18,19] yields c… Show more

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Cited by 3 publications
(4 citation statements)
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“…To improve the mechanical properties of the acid-tethered block copolymers, crystalline hydrophobic blocks with high T g were tested. These effectively mitigated the swelling behavior; however, obtaining equilibrium morphologies with thermal annealing became difficult. More complex block architectures were also envisaged, as shown by the representative examples in Figure b–d. , Placing the acid-tethered polymers in the midblock and hydrophobic polymers at both ends of the triblock copolymers created firm bridges. …”
Section: Synthesis Of Acid-tethered Block Copolymers: Passion For Ach...mentioning
confidence: 99%
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“…To improve the mechanical properties of the acid-tethered block copolymers, crystalline hydrophobic blocks with high T g were tested. These effectively mitigated the swelling behavior; however, obtaining equilibrium morphologies with thermal annealing became difficult. More complex block architectures were also envisaged, as shown by the representative examples in Figure b–d. , Placing the acid-tethered polymers in the midblock and hydrophobic polymers at both ends of the triblock copolymers created firm bridges. …”
Section: Synthesis Of Acid-tethered Block Copolymers: Passion For Ach...mentioning
confidence: 99%
“…The current research progress in acid-tethered polymers is closely related to the controlled synthesis of high-precision polymers with tailor-made monomers. To date, various types of acid moieties have been added to several polymers with tunable glass transition temperatures ( T g ) and polarities. This has enabled the high-yield preparation of proton-conducting polymers with linear diblock, ,, triblock, , pentablock, , and comb shapes . Therefore, the exploration of the structure–transport relationship became possible.…”
mentioning
confidence: 99%
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