Abstract:Effect of different chemicals and additives used in producing polyester foam was investigated. Reference samples were produced from polyol, toluene di isocyanate (TDI), amine stannous octoate distil water, and silicone oil using laboratory mix formulation based on 500 g polyether based polyol. Other samples were produced by consecutively varying the content of all the additives with the exception of polyol. Standard sample dimensions for density test, indentation test, compression set test, tensile strength an… Show more
“…They are produced as rovings, chopped strands, yarns, fabrics, and mats. Each type of glass fiber has unique properties, thus providing the possibility of various applications [ 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 ].…”
This study aims to analyze strength properties and low-cycle dynamic tests of composite materials modified with glass and basalt fibers. Biopolyamide 4.10 was used as the matrix, and the fiber contents were 15, 30, and 50% by weight. Static tensile tests, impact tests, and determination of mechanical hysteresis loops were carried out as strength tests. The length of the fibers in the produced composites and their processing properties were determined. The composite materials were compared with commercially available glass fiber-reinforced composites with 30 and 50% fiber contents. The results showed that such composites can successfully replace composite materials based on petroleum-based polymeric materials, providing high strength properties and reducing the negative environmental impact by using renewable sources. Composites with 30% basalt fiber composition were characterized by higher tensile strength by about 60% compared to commercially available composites with 30% glass fiber composition and an almost doubly increased Young’s modulus. Increasing the content of basalt fibers to 50% results in a further increase in strength properties. Despite the lower tensile strength compared to polyamide 6 with 50% glass fiber content, basalt fibers provided an approximately 10% higher modulus of elasticity.
“…They are produced as rovings, chopped strands, yarns, fabrics, and mats. Each type of glass fiber has unique properties, thus providing the possibility of various applications [ 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 ].…”
This study aims to analyze strength properties and low-cycle dynamic tests of composite materials modified with glass and basalt fibers. Biopolyamide 4.10 was used as the matrix, and the fiber contents were 15, 30, and 50% by weight. Static tensile tests, impact tests, and determination of mechanical hysteresis loops were carried out as strength tests. The length of the fibers in the produced composites and their processing properties were determined. The composite materials were compared with commercially available glass fiber-reinforced composites with 30 and 50% fiber contents. The results showed that such composites can successfully replace composite materials based on petroleum-based polymeric materials, providing high strength properties and reducing the negative environmental impact by using renewable sources. Composites with 30% basalt fiber composition were characterized by higher tensile strength by about 60% compared to commercially available composites with 30% glass fiber composition and an almost doubly increased Young’s modulus. Increasing the content of basalt fibers to 50% results in a further increase in strength properties. Despite the lower tensile strength compared to polyamide 6 with 50% glass fiber content, basalt fibers provided an approximately 10% higher modulus of elasticity.
“…In the quest for the replacement of metals in demanding applications in defence and aerospace, together with excellent strength and light weight urged chemists to develop different matrix resin systems and a wide variety of both inorganic and organic fibres with broad spectrum of tailorable properties. 1,2 Hence development of composites having applications in various engineering fields along with good thermal stability and having ability to serve continuously at high temperature (above 250°C) is continuing. 3,4 Still there exists heavy demand for resin systems having lower cure temperature but higher thermal stability or degradation temperature.…”
The materials 2,2-bis [4-(4-maleimidophenoxy phenyl)] propane (BMIX) and bisphenol-A based cyanate ester (BCY) were synthesized. The monomers BMIX and BCY were physically blended (BMCY) in 1:1 mol ratio. The materials BMIX, BCY and BMCY were thermally polymerized and the structural characterisation of the materials was done using Fourier transform infrared spectrophotometer (FTIR). The curing characteristics of BMIX, BCY and its blend (BMCY) were investigated using differential scanning calorimeter (DSC). The blend BMCY shows considerable differences in the thermal curing behaviour as evidenced by the DSC studies. Blending BCY with BMIX drastically reduces the melting temperature, curing onset temperature and the amount of heat liberated during thermal curing. The thermal stabilities of the crosslinked network polymers (PBMIX, PBCY and PBMCY) were investigated using thermogravimetric analyser (TGA). Detailed TGA studies indicated that the PBMCY shows better thermal stability than the PBMIX and PBCY. The DSC and TG curves indirectly hint about the possible reaction between BMIX and BCY during thermal curing. Woven glass fibre reinforced laminates were prepared using BMIX, BCY and BMCY by solution impregnation followed by drying and compression moulding. The glass laminate having BMCY as the matrix resin showed much better mechanical property (tensile strength) compared to the laminate made using BMIX as the matrix resin.
“…19,20 The use of glass fibers as reinforcement for many thermoplastics, especially the use of E-glass for relatively strong and lightweight plastic composites, has been reported. [21][22][23] They have applications in areas such as home and furniture, boats and marine, aviation and aerospace, automotive components, etc. 24 Recycling is a process aimed at recovering reusable parts and processable materials.…”
In the present work, a combination of virgin polypropylene and E-glass fiber was subjected to ten (10) reprocessing cycles via extrusion and compression molding techniques to mimic recycling and its impacts on the bending properties of the composites. The samples were characterized using Fourier transform infrared (FTIR) spectroscopy, x-ray diffraction (XRD), scanning electron microscopy (SEM), and melt flow index (MFI). The results revealed a gradual depreciation in flexural properties after each reprocessing cycle. The XRD analysis indicated a substantial reduction of peak intensities, degrees of crystallinities, and average crystallite sizes, explaining the lowered flexural properties in addition to a possible reduction in glass fiber lengths (fiber attrition). Melt-processing behavior shows a progressive increase of MFI from 7 to 19.16 g/10 min, confirming the probable damage in molecular weight and loss of complex viscosity. Chemical and structural analysis showed no alteration in the polypropylene major functional groups. It is concluded that the reductions in molecular weight and composites’ properties occurred due to chain scission from recycling effects; hence, glass fiber-reinforced polypropylene composites can be recycled only three (3) times unless it is refreshed by the addition of virgin parts to compensate for the lost property.
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