Two renormalization group invariant quantities in quantum chromodinamics (QCD), defined in Euclidean space, namely, Adler Dfunction of electron-positron annihilation to hadrons and Bjorken polarized deep-inelastic scattering sum rule, are considered. It is shown, that the 5-th order corrections to them in MS-like renormalization prescriptions, proportional to Riemann ζ-function ζ (4), can be restored by the transition to the C-scheme, with the β-function, analogous to Novikov, Shifman, Vainshtein and Zakharov exact β-function in N = 1 supersymmetric gauge theories. The general analytical expression for these corrections in SU (N c ) QCD is deduced and their scale invariance is shown. The β-expansion procedure for these contributions is performed and mutual cancellation of them in the 5-th order of the generalized Crewther identity are discussed.