The
physicochemical and electrical properties of Pt/Al-doped TiO2 (ATO)/Ru/TiN capacitors were investigated by adopting an
atomic-layer-deposited Ru interlayer between the ATO and the TiN layers.
The Ru interlayer induced local-epitaxial growth of the ATO films
to the rutile phase, resulting in improved electrical properties.
The work function and surface morphology of the Ru/TiN bottom electrode
affected the electrical properties of the capacitors. When the Ru
interlayer was too thin (<1.5 nm) to completely cover the entire
TiN surface, a mixture of rutile/anatase/amorphous ATO dielectric
films was grown, resulting in negligible improvement in the electrical
properties. With an increased Ru interlayer thickness, the work function
of the bottom electrode increased and the crystallinity of the rutile
ATO film was improved. However, when the Ru interlayer was too thick,
the capacitors became degraded because of the rough surface morphologies
of the electrode and dielectric films. Consequently, the improvement
of the electrical performances was maximized with a Ru interlayer
thickness of ∼2.5 nm. The achieved minimum equivalent oxide
thickness (EOT) was ∼0.52 nm with a low leakage current density
(<10–7 A/cm2 at a capacitor voltage
of 0.8 V). This performance was comparable to that of a bulk Ru bottom
electrode.