2014
DOI: 10.1021/am5075612
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Optimization of ZnxFe3–xO4 Hollow Spheres for Enhanced Microwave Attenuation

Abstract: We report here the composition optimization of Zn(x)Fe(3-x)O4 hollow nanospheres for enhancing microwave attenuation. Zn(x)Fe(3-x)O4 hollow nanospheres were synthesized through a simple solvothermal process. The maximum magnetization moment of 91.9 emu/g can be obtained at x = 0.6. The composite filled with Zn0.6Fe2.4O4 exhibited the bandwidth of 3.21-8.33 GHz for RL < -10 dB and a maximum relative bandwidth (Wp,max) of 88.6% at optimized thickness t0 = 0.34 cm. The enhancement should be attributed to the enha… Show more

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Cited by 72 publications
(24 citation statements)
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“…13.0 GHz, which can be ascribed to the natural resonance as reported elsewhere11. Because of the little difference in magnetization, we can find that the discrepancy of complex permeability is unobvious74.…”
Section: Discussionsupporting
confidence: 79%
“…13.0 GHz, which can be ascribed to the natural resonance as reported elsewhere11. Because of the little difference in magnetization, we can find that the discrepancy of complex permeability is unobvious74.…”
Section: Discussionsupporting
confidence: 79%
“…[20][21][22][23][24][25][26][27][28] Hollow structures exhibit special physical and chemical properties due to their low density and large surface area, having attracted attention as candidates for microwave absorption in recent years. [29][30][31] Zhao et al prepared the hollow three-dimensional CuS hierarchical microspheres and the effective bandwidth was 3.0 GHz with absorber thickness of 1.1 mm. 32 Considering the outstanding properties of graphene as well as hollow structures, hollow structures/graphene hybrids would be very attractive for practical applications.…”
Section: Introductionmentioning
confidence: 99%
“…Metallic oxide may be candidates for EM wave attenuation at high temperature. [21][22][23][24][25][26][27][28] Nonetheless, it is difficult for them to achieve high-efficiency EM wave attenuation due to weak electrical properties. Searching for high-efficiency EM wave attenuation materials, therefore, is still a highly challenging task, which only becomes more difficult in view of the stabilization of attenuation at high temperature.…”
Section: Introductionmentioning
confidence: 99%