Optimization of Process Parameters and Kinetics Analysis of Cd Removal in ZnSO4 Production

Abstract

In order to optimize the process parameters of Cd removal in the ZnSO4 production process and study the mechanism of Cd removal reaction, the response surface methodology was used to arrange Cd removal experiments and analyze the optimal production conditions, and the mechanism of Cd removal was studied using kinetics. The results show that the optimal process conditions for Cd removal are as follows: reaction temperature 55 °C, reaction time 13.43 min, and the zinc powder dosage should be 2.14 times that of Cd; the main effects of the three variables from large to small are zinc powder dosage, reaction temperature and reaction time; Cd removal is a second-order reaction, and the activation energy of the reaction is 29.6986 kJ/mol, so the reaction conforms to the diffusion control mechanism.