Optimization of Esterification Reaction Conditions Through the Analysis of the Main Significant Variables

Abstract

Biodiesel production from residual sources is gaining considerable attention nowadays. Consequently, many different studies with in-depth analysis concerning the influence of the transesterification reaction conditions are available in the literature. However, further evaluation of the esterification of fatty acids in the biodiesel industry is still needed. In this study, different parameters influencing the esterification reaction behavior using ethanol as the alcohol and lauric acid as the FFA are analyzed through factorial design and ANOVA methodologies to verify which ones are significant in the reaction. In total, four parameters were evaluated: temperature, catalyst concentration, ethanol/FFA ratio, and ethanol/water ratio. The temperature and ethanol/water ratio had a major influence on the reaction, as increasing these parameters greatly improved reaction conversion. It was also verified that using hydrous ethanol in the esterification reaction is possible in some conditions.

Optimization of ethyl oleate from oleic acid and ethanol with Dean-Stark trap technology by response surface methodology

“…In the analysis of variance (ANOVA) [18] the F value represents the fit of the corresponding factor, and a larger F value would lead to a more significant corresponding factor. The p-value indicates the significance level of the model and parameters.…”