The Skorokhod embedding problem aims to represent a given probability measure on the real line as the distribution of Brownian motion stopped at a chosen stopping time. In this paper, we consider an extension of the weak formulation of the optimal Skorokhod embedding problem in Beiglböck, Cox & Huesmann [1] to the case of finitely-many marginal constraints 1 . Using the classical convex duality approach together with the optimal stopping theory, we establish some duality results under more general conditions than [1]. We also relate these results to the problem of martingale optimal transport under multiple marginal constraints.