C<sub>4</sub>F<sub>7</sub>N and C<sub>4</sub>F<sub>7</sub>N-CO<sub>2</sub> mixtures are considered as alternatives to SF<sub>6</sub> for use in medium voltage gas insulated switchgear applications (GIS), due to the low global warming potential and good dielectric properties of C<sub>4</sub>F<sub>7</sub>N. Current work is focused on the calculation of radiative properties (absorption coefficients) of C<sub>4</sub>F<sub>7</sub>N-CO<sub>2</sub> thermal plasma and computational fluid dynamics (CFD) simulations of free burning C<sub>4</sub>F<sub>7</sub>N-CO<sub>2</sub> arcs that are stabilized by natural convection. Absorption coefficients of C<sub>4</sub>F<sub>7</sub>N-CO<sub>2</sub> plasma used in the CFD model are derived from spectral absorption coefficients by Planck averaging. An optimization procedure has been applied to find the optimal number of spectral bands as well as spectral band interval boundaries. Radiation and flow model results for C<sub>4</sub>F<sub>7</sub>N-CO<sub>2</sub> in comparison to SF<sub>6</sub> and air are provided and discussed.