Optically transparent metal-containing polymer materials

Smagin, V. P.

doi:10.1134/s2079978013020039

Cited by 5 publications

(1 citation statement)

References 34 publications

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“…Metal-containing optical polymers selectively absorb or transmit electromagnetic radiation, exhibit luminescence, and conduct electric current [1][2][3][4][5]. The metal atoms in the polymers are incorporated in organic or inorganic compounds.…”

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Synthesis and absorption and luminescence spectra of poly(methyl methacrylate):Cd(Mn,Pb)S composites

et al. 2015

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The reaction of cadmium, manganese, and lead trifl uoroacetates with thioacetamide in methyl methacrylate yielded colloidal solutions of metal sulfi des with different Cd(II) : Mn(II) : Pb(II) molar ratios. The colloidal particles were separated from solutions and examined by electron microscopy. Glassy polymer composites poly(methyl methacrylate):Cd(Mn)S and poly(methyl methacrylate):Cd(Mn,Pb)S were prepared by thermal polymerization of methyl methacrylate in the bulk. The transmittance of the composites at wavelengths larger than 480 nm is 92% at the sample thickness of 0.40 cm. The luminescence of the composites in the visible range is associated with cadmium sulfi de. The corresponding absorption bands were recorded in the luminescence excitation spectra in the wavelength interval 300-450 nm. The effect of the matrix, Mn(II) and Pb(II) ions, and synthesis conditions on the absorption and luminescence properties of the composites was determined.

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Synthesis and absorption and luminescence spectra of poly(methyl methacrylate):Cd(Mn,Pb)S composites

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Synthetic Methodologies for Chelating Polymer Ligands: Recent Advances and Future Development

Джардималиева

Uflyand

2018

ChemistrySelect

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This review summarizes recent progress in synthetic methodologies of chelating polymer ligands such as linear, branched, cross‐linked, grafted polymers, polymer films, liquid crystal polymers, dendrimers, star‐shaped and hyperbranched polymers. The features of methods for producing chelating polymer ligands are considered in detail: free‐radical (co)polymerization, living/controlled radical, metathesis, grafted, chemical oxidized, microwave‐assisted and asymmetric polymerization, electropolymerization, cyclopolymerization, polycondensation, post‐polymerization modification, click chemistry methods and “green” synthesis. The main directions of the development of synthetic chemistry of chelating polymeric ligands are analyzed. The bibliography includes works published in the last five years.

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General Introduction

Джардималиева¹,

Uflyand²

2018

Chemistry of Polymeric Metal Chelates

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Optically transparent metal-containing polymer materials

Cited by 5 publications

References 34 publications

Synthesis and absorption and luminescence spectra of poly(methyl methacrylate):Cd(Mn,Pb)S composites

Synthesis and absorption and luminescence spectra of poly(methyl methacrylate):Cd(Mn,Pb)S composites

Synthetic Methodologies for Chelating Polymer Ligands: Recent Advances and Future Development

General Introduction

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