Photoelectrochemical etching of uniform prestructured silicon wafers in hydrofluoric acid containing solutions yields periodic structures that can be applied to two-and three-dimensional photonic crystals or microfluidics. Here we demonstrate experimentally macroporous silicon etching initiated by a nonuniform predefined lattice. For conveniently chosen parameters we observe a stable growth of pores whose geometrical appearance depends strongly on the spatially different nucleation conditions. Moreover, we show preliminary results on three-dimensionally shaped pores. This material can be used to realize hybrid photonic crystal structures and incorporate waveguides in three-dimensional photonic crystals. © 2005 American Institute of Physics. ͓DOI: 10.1063/1.2137688͔ Porous silicon, 1,2 and in particular, macroporous silicon, 3,4 has attracted a lot of attention as a unique possibility to structure silicon. 5 This material system has been applied to optical shortpass filters 6 as well as to twodimensional ͑2D͒ and three-dimensional ͑3D͒ photonic crystals. 7,8 All these applications depend on the uniformity of the porous material. This property results from the perfect, lithographically arranged, uniform inverted pyramids acting as nuclei for the pore growth and the self-stabilized photoelectrochemical etching process used. The so-manufactured 3D photonic crystals show complete band gaps of about 5%. Recently, we proposed large 3D photonic band gaps in diamondlike structures, which may be fabricated using complex structured silicon wafers. 9 Here we present a detailed investigation focused on spatially different nucleation conditions. A simple quadratic lattice with a basis of two nonequally sized inverted pyramids is defined. We will demonstrate under which experimental conditions a stable pore growth is observed. Moreover, the nonequally sized nuclei result in a significant initial offset in height between adjacent pores. We will answer the question of how this considerable difference is affected by the selfstabilized interaction between the pores. This approach is well suited to incorporate air defects in photonic band-gap materials in two and three dimensions acting as resonators or waveguides. In particular, this is a step towards the experimental realization of the predicted 2D photonic crystal hybrid structures suggested by Trifonov et al. 10 Typically macroporous silicon is grown in a photoelectrochemical etching process. 5 An arbitrary 2D lattice is defined lithographically on the ͑100͒-oriented n-type silicon wafer. A subsequent anisotropic etching in potassium hydroxide ͑KOH͒ forms inverted pyramids acting as nuclei for the pore growth. This structured frontside is exposed to hydrofluoric acid ͑HF͒. Illuminating the backside of the silicon wafer generates electron-hole pairs. The electrons are extracted by the applied anodic bias whereas the electronic holes-the minority charge carriers-diffuse through the whole wafer to the silicon electrolyte interface. Due to the depletion layer at this interface an e...