Optical reflectivity as a simple diagnostic method for testing structural quality of icosahedral quasicrystals

Abstract

The optical reflectivity of Al-based and Ti-based quasicrystalline and approximant samples were investigated versus the quality of their structural morphology using optical reflectometry, X-ray diffraction and transmission electron microscopy. The different structural morphologies were obtained using three different preparation processes : sintering, pulsed laser deposition and reactive cathodic magnetron sputtering. The work demonstrates that the canonical behaviour of icosahedral state in specular reflectivity is extremely sensitive to different and very fine aspects of the microstructure : sizes of grains smaller than 50 nm, slight local diffuse disorder and shifts away from the icosahedral crystallographic structure (approximants). The work explains why the optical properties of the same kind of quasicrystals found in literature sometimes reveal a different behaviour from one author to another. The study then confirms the work of some authors and definitely shows that the canonical behaviour of icosahedral state in specular reflectivity over the 30000 -50000 cm -1 domain is characterized by a decreasing function made of steps. It also shows that this behaviour can be interpreted thanks to the cluster hierarchy of the model of Janot.

Features of the Initial Stage of the Formation of Ti-Zr-Ni Quasicrystalline Thin Films

“…As was shown in [7], the films in the initial state actually turned out to be X-ray amorphous, which was also observed in [5,6]. According to scanning electron microscopy, the image of the surface of the initially deposited film (Fig.…”

“…In addition, the film-target saturated with tritium can be used as an important device of the neutron source generator based on the D-T reaction [5]. There are few works devoted to the formation of quasicrystalline coatings of the Ti-Zr-Ni system [5][6][7], in contrast to the Al-Cu-Fe system [8]. When deposited on a "cold" substrate, as a rule, the coating is always amorphous, and when deposited on a substrate heated to 500-700 C, it is difficult to maintain the required composition [5,6].…”

“…There are few works devoted to the formation of quasicrystalline coatings of the Ti-Zr-Ni system [5][6][7], in contrast to the Al-Cu-Fe system [8]. When deposited on a "cold" substrate, as a rule, the coating is always amorphous, and when deposited on a substrate heated to 500-700 C, it is difficult to maintain the required composition [5,6]. In our previous article [7], it was shown that under magnetron sputtering in a medium of purified argon at a pressure of 2•10 -1 Pa and deposition on the substrate at room temperature, the composition can be controlled; and by varying the temperature and duration of subsequent vacuum annealing, the required phase composition can be achieved.…”