Luminescence manometry
is most often realized by a spectral shift
of luminescence bands. Typically, the shift of spectrally narrow-band
emission is quantified, which is highly precise but not very sensitive
to pressure variations. Alternatively, the spectral shift of a broadband
emission may be exploited, which is more sensitive but less precise,
due to the difficulty in accurate determination of the band centroid.
In this work, a mixed approach is presented, combining the shift in
broadband chromium emission from the 4T2 → 4A2 level with a narrow-band neodymium emission
(4F3/2 → 4I11/2 transition), observed in the La3Ga5GeO14 spectrum. The resulting optical Nd3+-based manometer
demonstrates an absolute sensitivity of 2.92 cm–1/GPa for the 4F3/2 → 4I11/2 electronic transition. An additional advantage of using
this material is its negligible spectral shift with temperature, determined
in the T range of 77–343 K, making the pressure
readouts independent of this parameter (i.e., temperature variations).