“…Recently, metal tungstates have undergone many thorough investigations and are used in various fields such as X‐ray intensified screen, lasers, light‐emitting diodes (LED), and scintillator materials 1,2 . Among them, calcium tungstate is a self‐activated blue‐emitting luminescence material, and its luminescence properties could be altered by doping with rare earth ions 3–5 . CaWO 4 is a prototype of heavy‐metal metal tungsten family, which has potential application in various fields.…”