Optical properties and site distribution of Cr3+ ions in alkali-disilicate glasses

Rodrı́guez-Mendoza, U.R.; Lavı́n, V.; Martı́n, I.R.; Rodrı́guez, V.D.

doi:10.1016/j.jlumin.2003.07.002

Cited by 8 publications

(1 citation statement)

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“…for Cr 3+ doped phosphate [31], fluoride [32] and silicate glass [33], respectively. The relatively low S0 of Cr 3+ doped SBNACZ indicates a relatively low multi-phonon non-radiative relaxation rate, and that the relatively low QE is caused by another process, such as crossrelaxation.…”

Section: Resultsmentioning

confidence: 99%

Energy transfer in Cr and Nd co-doped Si-B-Na-Al-Ca-Zr-O glasses

Hughes

Curry

et al. 2020

Journal of Non-Crystalline Solids

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Cr and Nd co-doped glasses are potential gain media for solar pumped lasers (SPLs). Tanabe-Sugano analysis shows that Cr doped Si-B-Na-Al-Ca-Zr-O (SBNACZ) glass contains a mixture of Cr 3+ with octahedral coordination and Cr 6+ with unknown coordination. The crystal field parameters for Cr 3+ were Dq = 1574 cm-1 , B = 792.2 cm-1 , C = 3005 cm-1 and Dq/B = 1.99, indicating a low covalency of Cr-O bonds. We compared the quantum efficiency (QE) of Nd and Cr co-doped SBNACZ glass with Nd doped SBNACZ glass to determine the Cr 3+ →Nd 3+ transfer QE. The Cr2O3 content was fixed at 0.1 mol.% and the Nd2O3 content was varied between 0.1 and 1 mol.%. A maximum transfer QE of 20% was obtained at 0.5 mol.% Nd2O3. Cr 3+ →Nd 3+ energy transfer is dominated by the coulombic interaction mechanism. The clustering of Nd 3+ was a limiting factor for increasing the transfer QE with higher Nd 3+ concentrations.

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Section: Resultsmentioning

confidence: 99%