Optical Method for Detection and Classification of Heavy Metal Contaminants in Water Using Iso-pathlength Point Characterization

Abstract

Water pollution caused by hazardous substances, particularly heavy metal (HM) ions, poses a threat to human health and the environment. Traditional methods for measuring HM in water are expensive and time-consuming and require extensive sample preparation. Therefore, developing robust, simple, and sensitive techniques for the detection and classification of HM is needed. We propose an optical approach that exploits the full scattering profile, meaning the angular intensity distribution, and utilizes the iso-pathlength (IPL) point. This point appears where the intensity is constant for different scattering coefficients, while the absorption coefficient is set. The absorption does not affect the IPL point position, it only reduces its intensity. In this paper, we explore the wavelength influence on the IPL point both in Monte Carlo simulations and experimentally. Next, we present the characterization of ferric chloride (FeCl 2 ) by this phenomenon. Eventually, we exhibit the detection of FeCl 2 and intralipid mixed in concentrations of 50−100 and 20−30 ppm, respectively. These findings endorse the idea that the IPL point is an intrinsic parameter of a system serving as an absolute calibration point. The method provides an efficient way of differentiating contamination in water. Its characterization technique is easy, precise, and versatile making it preferable for water monitoring.

A fluorescent sensor array based on a single cucurbit[5]uril–truxene probe for simultaneous identification of five heavy metal ions

“…1 Thus, the sensitive and efficient detection of heavy metal ions (HMIs) is particularly important. A variety of detection methods, such as atomic absorption, 2 electrochemical sensing, 3 X-ray fluorescence, 4 and optical methods, 5 among others, have made remarkable progress and achievements. Among them, optical methods including the fluorescence method and colorimetry had the unique advantages of high selectivity, high sensitivity, low cost, and simple operation mode.…”