1996
DOI: 10.1364/ol.21.001099
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Optical dichroism of lithographically designed silver nanoparticle films

Abstract: Films of identically shaped, elongated, and parallel-oriented metal nanoparticles arranged in a regular pattern upon a transparent substrate were produced by use of electron-beam lithography. Because of the strong difference in the particles' polarizability components, the optical extinction spectra show strong dichroism. Moreover, one can shift the spectral position of the extinction maximum in a wide range from 480 to 600 nm by variation of the particles' aspect ratio. This result suggests that designed meta… Show more

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Cited by 144 publications
(96 citation statements)
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“…b ¼ c), for which the same sensitivity increase is reached already at a=c % 3. Spheriodal Ag nanoparticles with high aspect ratios have been manufactured by electron-beam lithography [22,23] and, recently, by colloidal synthesis [24], although their applicability as biochemical sensors has apparently not yet been explored. Interestingly, the NSL fabricated samples investigated in [6] had aspect ratios of the order 2 (in-plane width %100 nm, height %50 nm) corresponding to an approximate sensitivity increase of $62% relative to the spherical case.…”
Section: Resultsmentioning
confidence: 99%
“…b ¼ c), for which the same sensitivity increase is reached already at a=c % 3. Spheriodal Ag nanoparticles with high aspect ratios have been manufactured by electron-beam lithography [22,23] and, recently, by colloidal synthesis [24], although their applicability as biochemical sensors has apparently not yet been explored. Interestingly, the NSL fabricated samples investigated in [6] had aspect ratios of the order 2 (in-plane width %100 nm, height %50 nm) corresponding to an approximate sensitivity increase of $62% relative to the spherical case.…”
Section: Resultsmentioning
confidence: 99%
“…Au can become a good catalyst when present as small clusters [342] while as bulk matter it is the most inert material known to mankind [343]. Optical (see for instance plasmon excitations in small Ag particles [344,345]) and electronic properties (photoluminescence from quantum dots [346,347] and magnetism in metal clusters [348]) become widely adjustable through the particle size. Many of the physical and chemical properties can so far only be investigated with integrating techniques needing a considerable density of uniform particles.…”
Section: Discussionmentioning
confidence: 99%
“…The recombinant polypeptide 17H6 [MGH 10 SSGHIHM (AAAQEAAAAQAAAQAEAAQAAQ) 6 AGGYGGMG] was expressed from an E. coli expression host and purified by metal chelate affinity chromatography, as described previously. [44,45 ] The assembled nanostructure of 17H6 is strongly dependent on its microenvironment, and can be controlled by changes in the initial solution conditions, in which the assembly is conducted, particularly pH and temperature.…”
mentioning
confidence: 99%