We study modulation spectroscopy of the coherent population trapping resonances and the frequency shift's structure of a corresponding error-signal used to stabilize an atomic clock frequency. The analytical expression of the shift is obtained in the model of the double Λ-system of levels interacting with the asymmetric polychromatic optical field. They reveal that the error-signal frequency can be displaced from that of "0 − 0" transition unperturbed by the optical field, although the frequency is not sensitive to changes in its intensity. Along with this effect, the degree of sensitivity suppression decreases. The experiment with 87 Rb atoms in Ar-N2 buffer gas atomic cell shows how the displacement value depends on different parameters, such as the modulation frequency, the absorption level, and the laser frequency. The possible influence of the effect on the clocks' frequency stability and reproducibility are discussed.