1977
DOI: 10.1063/1.89468
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Optical attenuation in pure and doped fused silica in the ir wavelength region

Abstract: Infrared absorption spectra of GeO2-, P2O5-, and B2O3-doped fused silica and nondoped fused silica have been obtained in the 3–25-μm wavelength region. It is shown that the intrinsic infrared absorption loss of doped silica fiber increases by several orders of magnitude beyond 1.8–2.0 μm because of the overtone and combination tone vibrations of the SiO4 tetrahedron. The loss spectrum is affected by dopants, especially in the case of B2O3. The lower limit of attenuation in optical fiber is estimated to be abou… Show more

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Cited by 135 publications
(42 citation statements)
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“…Fibers with different core sizes and a similar index profile also give comparable edges to the SC spectrum, which downplays the significance of the bend-induced loss. The loss in this HiNL fiber is measured (Fig.4b) and shows consistency with the published loss of fused silica fiber due to vibrational absorption, which increases to ~40 dB/m around 3.0 µm [5]. Therefore, the SC spectrum at the long wavelength side is believed to result from the intrinsic loss in the silica fiber.…”
supporting
confidence: 57%
“…Fibers with different core sizes and a similar index profile also give comparable edges to the SC spectrum, which downplays the significance of the bend-induced loss. The loss in this HiNL fiber is measured (Fig.4b) and shows consistency with the published loss of fused silica fiber due to vibrational absorption, which increases to ~40 dB/m around 3.0 µm [5]. Therefore, the SC spectrum at the long wavelength side is believed to result from the intrinsic loss in the silica fiber.…”
supporting
confidence: 57%
“…The tails of the multi-phonon components at 2015, 2150, 2350, and 2405 cm -I , Table I, extend from about 1950 to 2600 cmThis spread covers the infrared absorption region in fused silica for which bands between 3.8 and 5 .pm (13 ) have been reported and assigned to two-,.three-, and four-phonon combinations of silica fundamentals. In the region above 2.0 m, the transmission loss of doped silica fibers is known to increase by several orders of magnitude because of multi-phonon combinations involving (13-15) silica fundamentals.…”
mentioning
confidence: 99%
“…(2) and (3) are the standards when the primary consideration is the glass stability. In (3), attention must be paid to the increase in infrared absorption losses [45] when a lot of B 2 O 3 is used, and the possibility of increasing R c depending on the combinations of Mg, Ca, and Al when multiple components are used.…”
Section: Discussionmentioning
confidence: 99%