2011
DOI: 10.1016/j.jallcom.2011.01.172
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Optical and thermal properties of P2O5–Na2O–CaO–Al2O3:CoO glasses doped with transition metals

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Cited by 23 publications
(10 citation statements)
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“…monovalent Cu 1+ and divalent Cu 2+ . The glasses containing Cu 2+ ions showed a broad absorption band and no absorption band was observed due to Cu 1+ ions in the UV-Visible region [23]. The free ion term of octahedral symmetry for Cu 2+ ion being 3d 9 in a ligand field, experiences a strong Jahn-Teller distortion which leads to the splitting of energy levels.…”
Section: Optical Absorptionmentioning
confidence: 97%
“…monovalent Cu 1+ and divalent Cu 2+ . The glasses containing Cu 2+ ions showed a broad absorption band and no absorption band was observed due to Cu 1+ ions in the UV-Visible region [23]. The free ion term of octahedral symmetry for Cu 2+ ion being 3d 9 in a ligand field, experiences a strong Jahn-Teller distortion which leads to the splitting of energy levels.…”
Section: Optical Absorptionmentioning
confidence: 97%
“…It is well known that copper exists in glasses the forms of Cu 2 + and Cu + ions. While Cu + ions have no absorption in the UV-VIS region, the Cu 2 + ions have a strong absorption [21]. The free ion term for Cu 2 + ion (3d 9 ) is 2 D. In a ligand field of octahedral symmetry the 2 D ground state splits into the e g and t 2g states.…”
Section: Discussionmentioning
confidence: 99%
“…Copper ions have been frequently used as paramagnetic probes for exploring the structure and properties of glasses. A large number of interesting studies are available on the environment of copper ion in glasses [19][20][21][22][23]. Thus, in glasses, copper ions exist in two stable ionic states, the divalent Cu 2 + and monovalent Cu + ions, and may also exist as metallic copper [19].…”
Section: Introductionmentioning
confidence: 99%
“…A maximum 3 • C temperature difference between the front glass and cell centre would have a negligible effect on the corresponding layer mass heat capacity value and further on (mc p ) ef. This is justified by studies evaluating the effect of temperature on material mass heat capacity and conductivity, such as [28], whereby the mass heat capacity and conductivity of the glass, which is the main contributor in (mc p ) ef , remains nearly constant in the temperature range of 20-70 • C, which is the typical PV temperature range observed during outdoor operation at a wide range of environmental conditions. The effect of 3 • C temperature difference on (mc p ) glass is estimated 0.5%.…”
Section: Of 20mentioning
confidence: 99%