Optical and scintillation properties of Sr 3 NbGa 3 Si 2 O 14 (SNGS) single crystal were evaluated for the first time and compared with those of La 3 Ta 0.5 Ga 5.3 Al 0.2 O 14 (LTGA), which was previously reported to exhibit such properties. SNGS showed ~80% optical transmittance at wavelengths longer than 250 nm. Under 250 nm excitation, a strong photoluminescence (PL) appeared at 400 nm with a primary decay time of 1.4 ns. In an X-ray-induced radioluminescence spectrum, an intense emission peak at 400 nm was observed, and the primary scintillation decay time was ~1.37 μs. Finally, the absolute scintillation light yield of SNGS turned out to be 850 photons/MeV, which was higher than that of LTGA.