Opportunities from Metal Organic Frameworks to Develop Porous Carbons Catalysts Involved in Fine Chemical Synthesis

Pérez‐Mayoral, Elena; Godino‐Ojer, Marina; Matos, Inês; Bernardo, María

doi:10.3390/catal13030541

Cited by 7 publications

(5 citation statements)

References 137 publications

(167 reference statements)

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“…Alternatively, MOFs can act as precursors for porous carbon catalytic structures. This is often achieved through pyrolysis, whereby the MOF is exposed to high temperatures under an inert atmosphere, producing carbons that can be impregnated with existing metal species within the MOF [87,88].…”

Section: Metal-organic Frameworkmentioning

confidence: 99%

A Comprehensive Review of Fine Chemical Production Using Metal-Modified and Acidic Microporous and Mesoporous Catalytic Materials

Lantos,

Kumar,

Saha

2024

Catalysts

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Fine chemicals are produced in small annual volume batch processes (often <10,000 tonnes per year), with a high associated price (usually >USD 10/kg). As a result of their usage in the production of speciality chemicals, in areas including agrochemicals, fragrances, and pharmaceuticals, the need for them will remain high for the foreseeable future. This review article assesses current methods used to produce fine chemicals with heterogeneous catalysts, including both well-established and newer experimental methods. A wide range of methods, utilising microporous and mesoporous catalysts, has been explored, including their preparation and modification before use in industry. Their potential drawbacks and benefits have been analysed, with their feasibility compared to newer, recently emerging catalysts. The field of heterogeneous catalysis for fine chemical production is a dynamic and ever-changing area of research. This deeper insight into catalytic behaviour and material properties will produce more efficient, selective, and sustainable processes in the fine chemical industry. The findings from this article will provide an excellent foundation for further exploration and a critical review in the field of fine chemical production using micro- and mesoporous heterogeneous catalysts.

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Section: Metal-organic Frameworkmentioning

confidence: 99%

A Comprehensive Review of Fine Chemical Production Using Metal-Modified and Acidic Microporous and Mesoporous Catalytic Materials

Lantos,

Kumar,

Saha

2024

Catalysts

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“…Depending on the composition of the MOFs, the resulting metal nanoparticles can be either single nanoparticles or bimetallic nanoparticles supported over the amorphous carbon. It has been known that amorphous carbon can act as a good support toward many catalytic reactions. − The bimetals supported over the carbonized MOFs can be exploited toward catalytic reactions where the differences in the catalytic activity of the different metals would be important.…”

Section: Multifunctional Catalytic Centers In Mofsmentioning

confidence: 99%

Bifunctional MOFs in Heterogeneous Catalysis

Natarajan,

Manna

2023

ACS Org. Inorg. Au

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The ever-increasing landscape of heterogeneous catalysis, pure and applied, utilizes many different catalysts. Academic insights along with many industrial adaptations paved the way for the growth. In designing a catalyst, it is desirable to have a priori knowledge of what structure needs to be targeted to help in achieving the goal. When focusing on catalysis, one needs to cope with a vast corpus of knowledge and information. The overwhelming desire to exploit catalysis toward commercial ends is irresistible. In today’s world, one of the requirements of developing a new catalyst is to address the environmental concerns. The well-established heterogeneous catalysts have microporous structures (<25 Å), which find use in many industrial processes. The metal–organic framework (MOF) compounds, being pursued vigorously during the last two decades, have similar microporosity with well-defined pores and channels. The MOFs possess large surface area and assemble to delicate structural and compositional variations either during the preparation or through postsynthetic modifications (PSMs). The MOFs, in fact, offer excellent scope as simple Lewis acidic, Brönsted acidic, Lewis basic, and more importantly bifunctional (acidic as well as basic) agents for carrying out catalysis. The many advances that happened over the years in biology helped in the design of many good biocatalysts. The tools and techniques (advanced preparative approaches coupled with computational insights), on the other hand, have helped in generating interesting and good inorganic catalysts. In this review, the recent advances in bifunctional catalysis employing MOFs are presented. In doing so, we have concentrated on the developments that happened during the past decade or so.

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“…Hence, they are suitable for electrochemical reactions in the formation process of zinc–air batteries. The synthesis route for creating metal-based catalysts using Fe/Co/Ni/Zn involves mixing the two components, metal ions, and linker, under appropriate conditions so that porous crystalline structures are obtained [ 118 , 119 ].…”

Section: Performance In Zinc–air Batteriesmentioning

confidence: 99%

(Fe-Co-Ni-Zn)-Based Metal–Organic Framework-Derived Electrocatalyst for Zinc–Air Batteries

Adhikari,

Chhetri,

Rai

et al. 2023

Nanomaterials

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Zinc–air batteries (ZABs) have garnered significant interest as a viable substitute for lithium-ion batteries (LIBs), primarily due to their impressive energy density and low cost. However, the efficacy of zinc–air batteries is heavily dependent on electrocatalysts, which play a vital role in enhancing reaction efficiency and stability. This scholarly review article highlights the crucial significance of electrocatalysts in zinc–air batteries and explores the rationale behind employing Fe-Co-Ni-Zn-based metal–organic framework (MOF)-derived hybrid materials as potential electrocatalysts. These MOF-derived electrocatalysts offer advantages such as abundancy, high catalytic activity, tunability, and structural stability. Various synthesis methods and characterization techniques are employed to optimize the properties of MOF-derived electrocatalysts. Such electrocatalysts exhibit excellent catalytic activity, stability, and selectivity, making them suitable for applications in ZABs. Furthermore, they demonstrate notable capabilities in the realm of ZABs, encompassing elevated energy density, efficacy, and prolonged longevity. It is imperative to continue extensively researching and developing this area to propel the advancement of ZAB technology forward and pave the way for its practical implementation across diverse fields.

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Opportunities from Metal Organic Frameworks to Develop Porous Carbons Catalysts Involved in Fine Chemical Synthesis

Cited by 7 publications

References 137 publications

A Comprehensive Review of Fine Chemical Production Using Metal-Modified and Acidic Microporous and Mesoporous Catalytic Materials

A Comprehensive Review of Fine Chemical Production Using Metal-Modified and Acidic Microporous and Mesoporous Catalytic Materials

Bifunctional MOFs in Heterogeneous Catalysis

(Fe-Co-Ni-Zn)-Based Metal–Organic Framework-Derived Electrocatalyst for Zinc–Air Batteries

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