Intermediate fuel oils (IFOs) are frequently used as a carburant for ship engines. To achieve the desired viscosity specification, marine fuels are often produced by blending heavy residua and other refinery byproduct with distillate gas oil (MGO). The effects of both pressure and temperature on the bulk modulus and other physicochemical properties of light petroleum diesel fuels and biodiesel fuels have been extensively studied. On the contrary, less attention has been devoted to the study of the bulk modulus and viscous properties of heavier petroleum fuels, such as IFO grades. The overall objective of this work was to model the temperatureÀpressureÀviscosity dependence of common IFOs as a function of their molecular parameters. With this aim, the temperatureÀpressure dependence of the bulk modulus was modeled from pressureÀvolumeÀtemperature (PVT) data, using the Murnaghan equation of state. Finally, using both rheological and PVT data, the FillersÀMoonanÀTschoegl (FMT) equation was used for modeling the pressureÀtemperatureÀviscosity behavior of these fuel oils.
' INTRODUCTIONIntermediate fuel oils (i.e., IFO180 and IFO380) are frequently used as a carburant for ship engines. To achieve the desired viscosity specification, marine fuels are often produced by blending heavy residua and other refinery byproducts with distillate gas oil (MGO). From a chemical point of view, they are complex and variable mixtures of alkanes, alkenes, cycloalkanes, and aromatic hydrocarbons, containing low percentages of sulfur, nitrogen, and oxygen compounds. 1 The annual consumption of marine fuel oils in diesel engines is estimated at about 281 million tons, with the majority being IFO grades. 2 The performance of an injection-type compression ignition engine is highly dependent upon the physicochemical properties of the fuel, such as density, heat capacity, bulk modulus, and viscous properties. Particularly, the bulk modulus plays an important role in modeling and design of the injection system. Among other factors, the injection pressure and its evolution during the injection period depend upon the bulk modulus. 3 The effects of both pressure and temperature on the bulk modulus and other physicochemical properties of light petroleum diesel fuels and biodiesel fuels have been extensively studied, using techniques based on the speed of sound 4À6 and direct volume compression. 7 Nevertheless, less attention has been devoted to the study of the bulk modulus and viscous properties of heavier petroleum fuels, such as IFO grades.Knowledge of high-pressure viscous behavior and volumetric properties of these fuel oils is a very important issue not only for designing and simulating injection combustion systems but also for designing manipulating operations (pumping, extraction, etc.) and recovering fuel operations after an accident, as in the case of deep oil spills such as the "Prestige" tanker, 8 where modeling the temperatureÀpressure (TP) behavior or the heavy fuel remaining in the tank from the shipwreck to the ambient TP condition...