“…The PMRs utilizing catalyst in suspension that are described in literature have been applied to liquid phase photodegradation of humic [15][16][17][18] and fulvic [19] acids, bisphenol A [20,21], phenol [1], 4-nitrophenol [2], 4-chlorophenol [18], pharmaceutical and diagnostic residues [22][23][24], grey water from domestic washing operations [25], para-chlorobenzoate [26], river water [27], dyes [1,12,18,[28][29][30] and many other pollutants. Most of these PMRs combine photocatalysis with pressure driven membrane processes such as microfiltration (MF) [15,[18][19][20][21][22][25][26][27][28], ultrafiltration (UF) [1,16,17,29,30] and nanofiltration (NF) [1,2,12,23,24].…”
Section: Introductionmentioning
confidence: 99%
“…Most of these PMRs combine photocatalysis with pressure driven membrane processes such as microfiltration (MF) [15,[18][19][20][21][22][25][26][27][28], ultrafiltration (UF) [1,16,17,29,30] and nanofiltration (NF) [1,2,12,23,24]. However, when a catalyst in suspension is applied, the membrane fouling is observed, especially in case of MF and UF membranes.…”
“…The PMRs utilizing catalyst in suspension that are described in literature have been applied to liquid phase photodegradation of humic [15][16][17][18] and fulvic [19] acids, bisphenol A [20,21], phenol [1], 4-nitrophenol [2], 4-chlorophenol [18], pharmaceutical and diagnostic residues [22][23][24], grey water from domestic washing operations [25], para-chlorobenzoate [26], river water [27], dyes [1,12,18,[28][29][30] and many other pollutants. Most of these PMRs combine photocatalysis with pressure driven membrane processes such as microfiltration (MF) [15,[18][19][20][21][22][25][26][27][28], ultrafiltration (UF) [1,16,17,29,30] and nanofiltration (NF) [1,2,12,23,24].…”
Section: Introductionmentioning
confidence: 99%
“…Most of these PMRs combine photocatalysis with pressure driven membrane processes such as microfiltration (MF) [15,[18][19][20][21][22][25][26][27][28], ultrafiltration (UF) [1,16,17,29,30] and nanofiltration (NF) [1,2,12,23,24]. However, when a catalyst in suspension is applied, the membrane fouling is observed, especially in case of MF and UF membranes.…”
“…In addition, the permeate flux rate of MF membrane was improved when the commercial P25 was replaced by nano-structured TiO2, thus reducing the membrane fouling phenomenon. Similar integrative PMR configurations were also applied in other studies for the removal of virus [74], para-chlorobenzoate [75] and secondary effluent organics [76]. …”
Section: Integrative-type Pmrs With Suspended Photocatalystmentioning
confidence: 97%
“…Instable bubbles and turbulent flow generated by aeration exhibit a shearing effect that is conductive to removing the fouling layer and concentration polarization on the membrane surface. In a research conducted by Huang et al [75], an air-scouring pipe was applied below the membrane modules to produce coarse bubbles, which could strike the membrane fibers as well as attenuate membrane fouling. Du et al [115] applied bubbly flow to control membrane fouling under different aeration rate in an integrative PMR.…”
Abstract:The lack of access to clean water remains a severe issue all over the world. Coupling photocatalysis with the membrane separation process, which is known as a photocatalytic membrane reactor (PMR), is promising for water treatment. PMR has developed rapidly during the last few years, and this paper presents an overview of the progress in the configuration and operational parameters of PMRs. Two main configurations of PMRs (PMRs with immobilized photocatalyst; PMRs with suspended photocatalyst) are comprehensively described and characterized. Various influencing factors on the performance of PMRs, including photocatalyst, light source, water quality, aeration and membrane, are detailed. Moreover, a discussion on the current problems and development prospects of PMRs for practical application are presented.
“…The membrane could play the role of both a simple barrier for the photocatalyst and a selective barrier for the molecules to be degraded. Compared with conventional photoreactors, the combination of membranes with photocatalysts (membrane photocatalytic reactors, MPR) is advantageous in confining the photocatalyst within the reaction environment by the membrane, control of a residence time of molecules in the reactor and realization of a continuous process with simultaneous products separation from the reaction environment [6][7][8][9][10]. Therefore, the combination of two processes is commonly used for two major reasons: the enhancement of the removal of NOM, and the reduction of membrane fouling.…”
A flat submerged membrane combined with a TiO 2 /UV photocatalytic reactor (FSMPR) was employed in batch mode to remove humic acid (HA). HA removal efficiency was characterized by UV 254 absorbance, UV-vis spectra, dissolved organic carbon (DOC) concentration, specific UV absorbance (SUVA), and trihalomethane formation potential (THMFP). The FSMPR process was effective in removing more than 86% of DOC and nearly 100% of UV 254 absorbance, while the THMFPs of samples were reduced to < 19 µg/L after 150 min of treatment. In addition, changes in transmembrane pressure (TMP) with and without UV were evaluated; TiO 2 /UV was effective at controlling membrane fouling by HA. Analysis of the molecular weight (MW) distributions and three-dimensional excitation-emission matrix (EEM) fluorescence spectra of HAs revealed that the effectiveness in membrane fouling control is a result of changes in HA molecular characteristics. The TiO 2 /UV photocatalytic reactor caused the degradation of high MW, hydrophobic humic-like molecules to low MW, hydrophilic protein-like molecules, although this fraction was not completely removed during 150 min of treatment and was less responsible for membrane fouling.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.