Tritium movement and accumulation in a Next Generation Nuclear Plant with a hydrogen plant using a high-temperature electrolysis (HTE) process and a thermochemical water-splitting Sulfur-Iodine (SI) process are estimated by the numerical code THYTAN as a function of design, operational, and material parameters. Estimated tritium concentrations in the hydrogen product and in process chemicals in the hydrogen plant of the Next Generation Nuclear Plant using the HTE process are slightly higher than the drinking water limit defined by the U.S. Environmental Protection Agency and the limit in the effluent at the boundary of an unrestricted area of a nuclear plant as defined by the U.S. Nuclear Regulatory Commission. However, these concentrations can be reduced to within the limits through use of some designs and modified operations. Tritium concentrations in the Next Generation Nuclear Plant using the SI process are significantly higher as calculated and are affected by parameters with large uncertainties (i.e., tritium permeability of the process heat exchanger, the hydrogen concentration in the heat transfer and process fluids, the equilibrium constant of the isotope exchange reaction between HT and H 2 SO 4 ). These parameters, including tritium generation and the release rate in the reactor core, should be more accurately estimated in the near future to improve the calculations for the NGNP using the SI process. Decreasing the tritium permeation through the heat exchanger between the primary and secondary circuits may be an an effective measure for decreasing tritium concentrations in the hydrogen product, the hydrogen plant, and the tertiary coolant.iv v
EXECUTIVE SUMMARYThis study evaluated tritium concentrations in the hydrogen product and in process chemicals in the energy transport systems and the hydrogen plant associated with the Next Generation Nuclear Plant (NGNP). In this work, tritium generation and transport mechansisms in the NGNP are described. The mathematics of these mechanisms are outlined, and are then codified and analyzed using a Japan Atomic Energy Agency (JAEA) analysis code called THYTAN [Tritium and HYdrogen Transportation ANalysis code ]. As a preliminary step, the THYTAN code was benchmarked against data available from the Peach Bottom HTGR. After benchmarking, various configurations of the NGNP employing a hightemperature electrolysis (HTE) hydrogen plant and an NGNP employing a Sulfur-Iodine (SI) hydrogen plant were analyzed, and the concentrations of tritium in the process and product streams were compared to current regulatory effluent limits in ground water and in air.Tritium is generated in the core of the reactor from the ternary fission of nuclear fuel (e.g., e.g., 233 B. Tritium from these reactions diffuses from the core materials into the primary coolant, where it can migrate to other parts of the system through bulk transport, diffusion, and isotope exchange mechanisms. Tritium is lost from the system when it diffuses through barrier materials to the outside environ...